The stories will be curated by and told personally by Joe Elliott, Rick Savage, Rick Allen, Phil Collen and Vivian Campbell.
Produced and co-written by Def Leppard guitarist Phil Collen, 'Shock' is the Californian rockers' eighth studio album.
The band asked fans to submit videos of themselves singing along to the song for inclusion in the heartwarming new clip.
They will be joined by Roxy Music, The Zombies, Stevie Nicks and Radiohead in the prestigious Class Of 2019.
The song was originally lead single for Depeche Mode's 1990 album 'Violator', and has also been covered by Johnny Cash and Marilyn Manson.
Arguably Def Leppard's signature hit, 'Pour Some Sugar On Me' was first released in 1988 and hit No. 2 on the US Billboard Hot 100.
The tour's 58 dates realised total ticket sales of $97.1 million.
Both the new greatest hits collection and the 'Hysteria Singles Box' are slated for release on 30 November.
The legendary Sheffield hard rockers' most recent studio set was their self-titled 11th album from 2015.
The two-song session was taped in New York and will be aired at a later date as part of the streaming service's Singles series.
Styx, Joan Jett & The Blackhearts and Tesla are embarking on an extensive US tour running through May, June and July 2018
The full recording catalogue of British rock gods Def Leppard is available on streaming and download platforms from 19 January 2018.
Def Leppard have revealed they will be performing their classic album 'Hysteria' in its entirety during their tour dates in 2018
Sheffield rockers Def Leppard are in discussion with American band Journey to launch a major co-headlining tour of North America in 2018
Def Leppard's worldwide 30 million-seller Hysteria is to be reissued by in numerous formats and with newly-released and rare material on 4 August 2017.
Def Leppard lead guitarist Phil Collen has formed a new blues band, Delta Deep, whose first album has Joe Elliott, David Coverdale and Paul Cook guesting.