The ceremony, which honors the best in country music, broadcasts live from Nashville on April 18.
On Sunday, the country star delivered a triumphant performance with Jazmine Sullivan at Super Bowl LV.
The country hero and current CMA Entertainer of the Year wrote the track himself.
C2C was due to take place in March, and will now return over the weekend of March 11-13, 2022 in London, Glasgow and Dublin.
The rare, collaborative performance will mark the event’s first since 2006.
The star will be promoting his new album, 'The Speed Of Now Part 1', which debuted atop the Billboard 200 as well as the Australian charts.
The event, hosted by Reba McEntire and Darius Rucker, marked the first time the country community had come together in person for many months.
The awards will take place with all artists safely installed in one room, and will be broadcast in the US live from Nashville on November 11.
The album simultaneously arrives at No.7 on the all-genre Billboard 200.
Taking place in Nashville for the very first time, the 55th annual ACM Awards air on September 16.
It's another of the songs to come from an intensive creative writing and recording period early in 2020.
The lyrics of Church's song describe a tough, uncompromising female truck driver who is "hell on wheels."
At 73, Hubbard has landed a major label deal and made an album featuring Ringo Starr, Joe Walsh, the Cadillac Three and many others.
The country star describes the song as "the tip of the spear for what’s coming after, and it’s a big spear."
The three-hour special will feature more than 25 performances from past CMA Fests, including those by Darius Rucker, Carrie Underwood and Tim McGraw.
