The Irish star's new release will be released through Decca Records on 29 May.
The service launches today in the UK, Ireland, Germany, Italy, Spain, Austria, and Switzerland and arrives in France on 7 April.
Porter launched the series in August 2019, in a ten-week run that had him in conversation with Annie Lennox, Jeff Goldblum, Don Was and others.
The track comes on the heels of Goldblum's second No. 1 album in the jazz charts, 'I Shouldn’t Be Telling You This,' released on 1 November to widespread acclaim.
Today also saw the release of his new single, ‘The Cat’, a peppy jazz number that embodies Goldblum’s debonaire spirit.
The track also features on Goldblum's new album, 'I Shouldn't Be Telling You This', recorded with The Mildred Snitzer Orchestra.
Goldblum says: “The truly classic singers have that unmistakeable sound that grabs you immediately. Gregory Porter is one of those singers."
The new record also features guest slots from Anna Calvi, Fiona Apple, Inara George and more.
During the ten-week series, Porter will also meet such distinguished figures as Kamasi Washington, Charlotte Gainsbourg and Annie Lennox.
The actor and jazz musician revealed he has been back in the recording studio in LA with his long-time band The Mildred Snitzer Orchestra.
The star will celebrate songs written by fellow Irish artists such as Van Morrison, U2 and Thin Lizzy on the night.
Jeff Goldblum and the Mildred Snitzer Orchestra performed their song ‘My Baby Just Cares for Me’ with singer Haley Reinhart on 'Jimmy Kimmel Live!' on 8 November 2018.
Goldblum’s version of the evergreen standard is taken from his forthcoming Decca album ‘The Capitol Studio Sessions’.
The actor is accompanied by his longtime band the Mildred Snitzer Orchestra and guests including Imelda May.
The Hollywood star and jazz pianist will appear at Cadogan Hall in West London on 17 November.