The pre-recorded show will be broadcast at drive-ins across North America later this month.
The band’s upcoming live album and documentary, S&M² is scheduled to hit stores on August 28.
The concert is the latest pick in the band’s official ‘Metallica Mondays’ video series.
The show, recorded at the John Lennon Auditorio, is the latest in the band's on-going 'Metallica Mondays' archival video series.
The latest in the ‘Metallica Mondays’ livestream series features Kirk Hammett and Rob Trujillo covering The Stone Roses’ ‘I Wanna Be Adored’
The new collection draws inspiration from the band's biggest albums, including 1991’s 'Metallica (the Black Album)'.
Lars Ulrich says, “I can tell you that all four of us are really excited about what that could look like."
The band made the donation through its All Within My Hands non-profit foundation.
The film will now be returning for one more night in cinemas worldwide on 30 October.
It's become a tradition for Metallica to pay tribute to artists who come from the cities or the countries they are playing in.
The metal titans donated to Dublin's Capuchin day centre which helps provide for homeless people and the ISPCC for children.
The concert at Estadio Bicentenario de La Florida is being billed as Slayer's final performance in frontman Tom Araya's native country.
The film, which is directed by Adam Dubin, is set to premiere on 20 April at AMC Kabuki 8 in San Francisco.
The special, one-off event is to mark the 20th anniversary of the metal titans' 1999 live LP, 'S&M.'
The seventh annual Metallica night with baseball’s San Francisco Giants will take place on 26 April.