The track will be on June's third album 'The Moon and Stars: Prescriptions For Dreamers,' to be released on March 12.
The February 17 concert will also feature Angélique Kidjo, Valerie June, and Phoebe Bridgers.
June will mark the release with a guided, themed meditation from her home in Brooklyn.
The virtual ‘Farm Aid 2020 On the Road’ will feature performances from over 20 artists.
The original was on the 1970s glam-rock pacesetters' 1971 UK No. 1 album Electric Warrior.
The song, which has already attracted more than one hundred versions, is one of June's Hendrix favourites.
Valerie June, Bobby Rush, Amy LaVere and Luther Dickinson all contribute to Red Hot: A Memphis Celebration of Sun Records, from the Americana Music Society.
Bob Dylan reveals in a new interview that he's a fan of Irish singer-songwriter Imelda May and Mississippi native Valerie June.
Showcasing her new album, ‘The Order Of Time’, Valerie June storms London’s hottest new venue, the Omeara.