The Canadian star – who is nominated for International Male Solo Artist – will perform remotely due to the current coronavirus travel restrictions.
Rodrigo will join already-announced performers Arlo Parks, Dua Lipa, Griff, Headie One, and Rag'n'Bone Man and P!nk at the 2021 BRITS.
The newly-stripped back version of the song is also part of the British singer-songwriter's forthcoming Record Store Day release on June 12.
Pushed back three months due to the COVID-19 pandemic, this year's ceremony will now take place at London’s O2 Arena on May 11, 2021.
The fast-rising star also released her debut album, 'Not Your Muse' last week.
The rising singer-songwriter is set to play shows on three consecutive nights on July 6, 7 and 8.
The live-streamed show will see the duo playing in the unique setting of a National Park with the beauty of the natural world as a backdrop.
The track also features on the soundtrack of the new film 'EMPEROR', which will be released on EMI Records on August 7.
The entertainer is currently making a new, 'grand finale' album as a thank you to her fans and for her career.
In this form, the track was only previously available as a bonus on the Japanese edition of the band's latest album, 'Cause & Effect'.
The stream will air exclusively on the band's official YouTube Channel on August 1, 2020 at 12 p.m. PT.
Lewis Capaldi, Billie Eilish and Celeste were among the winning artists at this year’s ceremony.
The singer's new album 'What's Your Pleasure?' is due for release tomorrow, 26 June.
The new track is the singer-songwriter's first new music since his chart-topping debut album, 'Without Fear'.
The singer's new album, What's Your Pleasure?, is also set for release on 19 June.